Karakura School Gang
School Queen=Orihime Inoue
Queen's Right Hand=Tatsuki Arisawa
Tatsuki's Second Form=Karakura Raizer Savage Beast
Tatsuki's Third Form=Shinigami Tatsuki
First Branch Leader=Kyoko Haida
Kyoko's Zanpakutou=Mouthless Toju
First Branch Right Hand=Ryo Kunieda
First Branch Left Hand=Michiru Ogawa
Second Branch Leader=Chizuru Honsho
Chizuru's Second Form=Karakura Raizer Erotic
Second Branch Right Hand=Mahana Natsui
Second Branch Left Hand=Misato Ochi
Third Banch Head=Karin Kurosaki
Third Branch Right Hand=Ururu Tsumugiya
Ururu's Second Form=Karakura Raizer Tiny Devil
Third Branch Left Hand=Yuzu Kurosaki
Gotei Thirteen
Squad 1 Captain=Yoruichi Sihoin
Yoruichi's Second Form=Cat Yoruichi
Squad 2 Captain=Soifon
Soifon's Zanpakutou=Suzumebachi
Squad 3 Captain=Senna
Squad 4 Captain=Retsu Unohana
Squad 4 Lieutenant=Isane Kotetsu
Squad 5 Captain=Momo Hinamori
Momo's Zanpakutou=Tobiume
Squad 6 Captain=Lisa Yadomaru
Squad 7 Captain=Hiyori Sarugaki
Squad 8 Captain=Nanao Ise
Squad 9 Captain=Mashiro Kuna
Squad 10 Captain=Rangiku Matsumoto
Rangiku's Zanpakutou=Haineko
Squad 11 Captain=Yachiru Kusajishi
Yachiru's Second Form=Adult Yachiru
Squad 12 Captain=Nemu Kurotsuchi
Squad 13 Captain=Rukia Kuchiki
Rukia's Zanpakutou=Sode no Shirayuki
Rukia's Second Form=Dark Rukia
Squad 13 Lieutenant=Kiyone Kotetsu
Espada
Cero Espada=Tia Halibel
Halibel's Second Form=Tiburon
Primera Espada=Neliel Tu Odershvank
Neliel's Second Form=Gomuza
Segunda Espada=Masaki Kurosaki
Masaki's Second Form=
Trecera Espada(s)=Apache, Sun-Sun, and Mila-Rose
Apache's Second Form=Cierva
Sun-Sun's Second Form=Anaconda
Mila-Rose's Second Form=Leona
Quatro Espada=Cirucci Thunderwitch
Cirucci's Second Form=
5th Espada=Lilynette Gingerback
Lilynette's Second Form=Los Lobos
Sexta Espada(s)=Loly Aivirrne and Menoly Mallia
Loly's Second Form=
Menoly's Second Form=
7th Espada=Miyako Shiba
Miyako's Second Form=Glotoneria
Octava Espada(1)=Yin
Yin's Second Form=
Octava Espada(2)=Yang
Yang's Second Form=
Nueveno Espada=Unnamed Female Arrancar/Usagi
Usagi's Second Form=
Xcution
Leader=Titty Kubo
Second In Command=Yoshino Soma
Yoshino's Second Form=
Training Officer=Jackie Tristan
Training Officer=Riruka
Field Agent=Yoshi
Recruitment Officer=Ririn
Recruitment Officer=Ikumi Unagiya
Others((Most of these will be sorted into other categories later))
Kanisawa
Kukaku Shiba
Ran'Tao
Rurichiyo Kasumioji
Benin
Matsuri Kudo
Homura
Katen Kyokotsu
Saru & Hebi Zabimaru